Evaluation of the photocatalytic efficiency of cobalt oxide-reduced graphene oxide-banana biochar hybrid composite towards the degradation of organic dyes and heavy metal Chromium (VI)

Amrita priyadarsini1, Chirasmayee Mohanty2, Nigamananda Das2, Nandita Swain1, Manasi Dash3, Abinash Mishra3, Pradip Kumar Jena1*and Spandan Nanda1

1Department of Chemistry, College of Basic Science and Humanities, Odisha University of Agriculture and Technology, Odisha. 2Department of Chemistry, Utkal University, Bhubaneswar 751004, Odisha. 3Department of Genetics and Plant Breeding, Odisha University of Agriculture and Technology, Odisha. Corresponding e-mail: pradip_callme@yahoo.co.in, nanda.spandan56@gmail.com

DOI: https://doi.org/10.37855/jah.2024.v26i01.18

Key words: Biochar, nanocomposites, photocatalysis, heavy metals, industrial dye, sustainable
Abstract: For a realistic solution, the synthesis of a cost-effective and efficient photocatalyst for the environmental need is utmost essential. Here, a simple in situ hydrothermal method that is a type of “green synthesis” since it doesn’t require harmful chemicals was used to synthesise the simple catalyst Co3O4/reduced graphene oxide/biochar (CBG). The Co3O4 nanoparticles are finely distributed over the sheets of reduced graphene oxide and biochar during the morphological examination, making the composite stable and appropriate for environmental applications. This catalyst was specifically used to create a Z-scheme heterostructure composite that significantly improves the Co3O4 and biochar/rGO photocatalytic performance when exposed to visible light. When it comes to dye and heavy metal Chromium (VI) degradation, the catalyst composite exhibited significantly greater catalytic efficacy compared to individual catalysts. The structural, morphological, and optical features of the CBG nanocomposite were primarily responsible for its exceptional visible light photocatalytic activity with a maximum kinetic rate constant. By optimising the catalyst ratio, the herein described technology can be used to create a promising photocatalyst for environment friendly and sustainable development.



Journal of Applied Horticulture